Ethylene Oxide and Ethylene Glycol Production Process

Ethylene Oxide and Ethylene Glycol Production Process

Ethylene Oxide (EO) and Ethylene Glycol (EG) production is a core operation in modern petrochemical complexes, supplying essential intermediates for polyester, antifreeze, resins, solvents, and industrial chemicals.

Ethylene Oxide (EO) and Ethylene Glycol (EG) production is a core operation in modern petrochemical complexes, supplying essential intermediates for polyester, antifreeze, resins, solvents, and industrial chemicals.

The primary objective of EO/EG production units is to efficiently convert ethylene into high-purity ethylene oxide and downstream ethylene glycols while ensuring safe operation, high on-stream availability, and competitive production economics.

EO and EG plants are typically designed as integrated units, allowing direct conversion of ethylene oxide into Mono-Ethylene Glycol (MEG), Di-Ethylene Glycol (DEG), and Tri-Ethylene Glycol (TEG).

Commercial plants focus on maximizing selectivity, minimizing by-product formation, and achieving long catalyst life cycles.

Process
Objective

Convert ethylene into high-purity ethylene oxide and downstream glycols with maximum selectivity and long catalyst life.

Main
Products

Ethylene Oxide (EO), Mono-Ethylene Glycol (MEG), Di-Ethylene Glycol (DEG), and Tri-Ethylene Glycol (TEG).

Commercial
Applications

Polyester, PET, antifreeze, resins, solvents, surfactants, and industrial chemicals.

Production Process Overview
Production Process
Overview
01

Step 1

Catalytic oxidation of ethylene to produce ethylene oxide.

02

Step 2

Controlled hydration of EO to produce MEG, DEG, and TEG.

03

Step 3

Separation and purification to commercial-grade products.

Ethylene Oxide Production
Ethylene Oxide
Production
01

Ethylene oxide is produced by the catalytic oxidation of ethylene using oxygen or air in the presence of a silver-based catalyst. The reaction is carried out in a fixed-bed tubular reactor designed for high heat removal efficiency and stable long-term operation.

02

Commercial Features:

01High ethylene conversion with controlled selectivity
02Continuous operation with optimized heat recovery
03Integrated recycle and purification systems
04Licensed and proven industrial technology

03

EO production units are designed to meet strict safety standards due to the reactive nature of ethylene oxide.

Ethylene Glycol Production
Ethylene Glycol
Production
01

Ethylene glycol is produced by the controlled hydration of ethylene oxide, followed by separation and purification.

02

Key Outputs:

01Mono-Ethylene Glycol (MEG)
02Di-Ethylene Glycol (DEG)
03Tri-Ethylene Glycol (TEG)

03

Commercial EG units are optimized to maximize MEG yield while allowing flexible DEG and TEG production based on market demand.

Licensed Technologies and Process Providers
Licensed Technologies
and Process Providers
Technology Base
Proven licensed EO/EG technologies.
Reactor design, catalyst systems, and heat integration.
Reliable, scalable, and globally accepted process packages.

EO/EG production is based on well-established licensed technologies supplied by globally recognized licensors.

Major Technology Providers:
Shell Global Solutions
Scientific Design (a Linde company)
Lummus Technology
Technip Energies
BASF

These licensors provide complete process packages including reactor design, catalyst systems, heat integration, and operational guidelines.

Catalysts
Catalysts
EO Production Selectivity
Catalyst Type
Silver-based catalysts supported on alumina.
Performance Goal
High selectivity and stable long-term operation.
Supply Support
Licensor-approved sourcing and logistics.

Catalysts are critical for achieving high selectivity and stable EO production.

Common Catalyst Systems:
Silver-based catalysts supported on alumina
Promoter-enhanced formulations for improved selectivity

Leading Global Catalyst Suppliers:
BASF
Shell Catalysts & Technologies
Scientific Design
Johnson Matthey

OGSCM Group supports EO/EG producers by sourcing and supplying licensor-approved catalysts with full technical documentation and logistics support.

Chemicals
Feedstock and
Process Chemicals
Primary Feedstock
High-purity ethylene (C₂H₄).
Process Utilities
Oxygen, CO₂, demineralized water, and caustic soda.
Supply Formats
Bulk, ISO tanks, IBC containers, and steel drums.

EO/EG production requires consistent supply of high-purity feedstock and auxiliary chemicals.

Key Chemicals Include:
Ethylene (C₂H₄) – primary feedstock
Oxygen / Air – oxidant for EO reactor
Carbon Dioxide (CO₂) – reaction moderation
Demineralized Water – EO hydration
Caustic Soda (NaOH) – neutralization and cleaning

Major Global Chemical Brands:
BASF
Dow
Shell Chemicals
SABIC
INEOS
LyondellBasell

OGSCM Group supplies EO/EG process chemicals in approved industrial packaging formats with full safety and technical documentation.