
Polyvinyl Chloride (PVC) is a synthetic thermoplastic polymer produced by the polymerization of vinyl chloride monomers. It exists in two main forms: rigid (uPVC) and flexible (when plasticized). Rigid PVC is commonly used in pipes and profiles, while flexible PVC is used in cables, flooring, and synthetic leather. PVC is resistant to water, chemicals, and environmental degradation, but it can degrade under prolonged UV exposure unless stabilized.
Polyvinyl chloride (PVC) is one of the most widely used thermoplastic polymers, which is divided into different grades depending on the polymerization method and the type of end use. Among them, two common grades include Grade S (Suspension) and Grade E (Emulsion).
PVC Grades: Difference Between S and E
Grade S (Suspension PVC)
This type of PVC is produced through the suspension polymerization process and is supplied in powder form. Grade S has the largest market share and is used in the production of hard products such as construction pipes, window and door profiles, flooring, as well as soft products (if plasticizers are added). Parameters such as viscosity, particle size, and particle porosity are important technical characteristics of this grade.
Grade E (Emulsion PVC):
Grade E, also known as PVC paste, is produced by emulsion polymerization and is usually marketed as a paste or latex. Due to its very fine grain size, this type of PVC is used in more precise applications such as surface coatings, synthetic leather production, medical gloves and flexible flooring. Despite its high quality, this grade is more expensive to produce than Grade S.
Technical Characteristics
| Molecular formula | (C₂H₃Cl)ₙ |
| Density (gr/cm3) | 1.35 – 1.45 |
| Melting point | ~75 – 105°C (softens gradually) |
| Melt flow index at 230°C and 2.16 kg load | |
| Tensile strength | 35 – 60 (MPa) for rigid PVC |
| Vicat softening temperature | ~75 – 85°C |
| Appearance | Can be transparent or opaque; available in rigid or flexible forms |
Applications
- Pipes and fittings (plumbing, irrigation)
- Window and door profiles
- Electrical cable insulation
- Medical tubing and IV bags
- Flooring, wall coverings, and synthetic leather
- Packaging materials (blister packs, bottles)
- Credit cards and ID cards
Environmental Impact of PVC
PVC production involves chlorine and other additives, which can raise environmental concerns if not managed properly. Burning PVC releases harmful dioxins, making disposal a sensitive issue. While PVC is technically recyclable (coded as #3), the presence of additives complicates recycling processes. Sustainability efforts include developing cleaner production methods and improving closed-loop recycling systems.
Safety Measures and Regulations for Handling PVC
PVC is generally safe in end-use products but can release hazardous fumes (like HCl gas) if overheated during processing. Proper ventilation, use of PPE, and adherence to safety standards (e.g., OSHA, EPA, REACH) are critical. Special care is required in handling additives such as plasticizers and stabilizers.
Packing
PVC is typically supplied in 25 kg bags or bulk containers, available in powder, pellet, or compound form for extrusion, injection molding, or calendaring.
| PVC |
| S 57 |
| S 65 |
| S 70 |
| E 6834 |
